Search results for "Capacity loss"
showing 3 items of 3 documents
Sensitive magnetometry reveals inhomogeneities in charge storage and weak transient internal currents in Li-ion cells
2020
The ever-increasing demand for high-capacity rechargeable batteries highlights the need for sensitive and accurate diagnostic technology for determining the state of a cell, for identifying and localizing defects, and for sensing capacity loss mechanisms. Here, we leverage atomic magnetometry to map the weak induced magnetic fields around Li-ion battery cells in a magnetically shielded environment. The ability to rapidly measure cells nondestructively allows testing even commercial cells in their actual operating conditions, as a function of state of charge. These measurements provide maps of the magnetic susceptibility of the cell, which follow trends characteristic for the battery materia…
Exploring High-Energy Li-I(r)on Batteries and Capacitors with Conversion-Type Fe3O4-rGO as the Negative Electrode
2017
We report a microwave-assisted solvothermal process for the preparation of magnetite (Fe3O4, ca. 5 nm)-anchored reduced graphene oxide (rGO). It has been examined as a prospective conversion-type negative electrode for multiple energy storage applications, such as Li-ion batteries (LIBs) and Li-ion capacitors (LICs). A LiFePO4/Fe3O4-rGO cell is constructed and capable of delivering an energy density of approximately 139 Wh kg−1 with a notable cyclability (ca. 76 %) after 500 cycles. Prior to the fabrication of a LIB, the Fe3O4-rGO is electrochemically pretreated to eliminate the irreversible capacity loss. In addition to the LIB, a high-energy LIC is also fabricated by using the pre-lithiat…
Statistical Analysis of the Channel Capacity Outage Intervals in Massive MIMO Systems with OSTBC over Rayleigh Fading Channels
2015
This paper studies approximate solutions for the statistical properties of the outage intervals of the instantaneous capacity in massive multiple- input multiple- output (MIMO) sys- tems with orthogonal space-time block code (OSTBC) over Rayleigh fading channels. We take advantage from the fact that the probability density function (PDF) of the channel power gain can be approximated by a left-truncated Gaussian distribution if the number of transmit and receive antennas is large. Assuming a symmetrical Doppler power spectral density (PSD), a closed- form expression is presented for the Rice probability function of the outage durations. This function, in general, approximates the PDF of the …